Can you link Shopify to either a Starling or Transferwise business account?

They do both have physical addresses. You can find the physical address on your app.

I have an account with Revolut and Shopify accepted it, so you shouldn't have any issues.

Yes, both Transferwise and Starling business account are linkable with Shopify. Now that both of these options are available, the question is which one should you use – Shopify Transferwise vs Starling.

I prefer using Starling over Transferwise for Shopify payments. The reason is that Transferwise Shopify payments cost you more fees in terms of money transfer, currency conversions, and ATM withdrawals than Starling. Hence, Starling is cost-efficient.